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Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

《能源前沿(英文)》 2018年 第12卷 第1期   页码 43-71 doi: 10.1007/s11708-018-0524-8

摘要: Vibrational spectroscopy is one of the key instrumentations that provide non-invasive investigation of structural and chemical composition for both organic and inorganic materials. However, diffraction of light fundamentally limits the spatial resolution of far-field vibrational spectroscopy to roughly half the wavelength. In this article, we thoroughly review the integration of atomic force microscopy (AFM) with vibrational spectroscopy to enable the nanoscale characterization of emerging energy materials, which has not been possible with far-field optical techniques. The discussed methods utilize the AFM tip as a nanoscopic tool to extract spatially resolved electronic or molecular vibrational resonance spectra of a sample illuminated by a visible or infrared (IR) light source. The absorption of light by electrons or individual functional groups within molecules leads to changes in the sample’s thermal response, optical scattering, and atomic force interactions, all of which can be readily probed by an AFM tip. For example, photothermal induced resonance (PTIR) spectroscopy methods measure a sample’s local thermal expansion or temperature rise. Therefore, they use the AFM tip as a thermal detector to directly relate absorbed IR light to the thermal response of a sample. Optical scattering methods based on scanning near-field optical microscopy (SNOM) correlate the spectrum of scattered near-field light with molecular vibrational modes. More recently, photo-induced force microscopy (PiFM) has been developed to measure the change of the optical force gradient due to the light absorption by molecular vibrational resonances using AFM’s superb sensitivity in detecting tip-sample force interactions. Such recent efforts successfully breech the diffraction limit of light to provide nanoscale spatial resolution of vibrational spectroscopy, which will become a critical technique for characterizing novel energy materials.

关键词: vibrational spectroscopy     atomic force microscopy     photo-thermal induced resonance     scanning near-field optical microscopy     tip-enhanced Raman spectroscopy     photo-induced force microscopy     molecular resonances     surface phonon polaritons     energy materials    

Thermal reffusivity: uncovering phonon behavior, structural defects, and domain size

Yangsu XIE, Bowen ZHU, Jing LIU, Zaoli XU, Xinwei WANG

《能源前沿(英文)》 2018年 第12卷 第1期   页码 143-157 doi: 10.1007/s11708-018-0520-z

摘要: To understand the relation between different nanostructures and thermal properties, a simple yet effective model is in demand for characterizing the underlying phonons and electrons scattering mechanisms. Herein, we make a systematic review on the newly developed thermal reffusivity theory. Like electrical resistivity which has been historically used as a theory for analyzing structural domain size and defect levels of metals, the thermal reffusivity can also uncover phonon behavior, structure defects and domain size of materials. We highlight that this new theory can be used for not only metals, but also nonmetals, even for amorphous materials. From the thermal reffusivity against temperature curves, the Debye temperature of the material and the ideal thermal diffusivity of single perfect crystal can be evaluated. From the residual thermal reffusivity at the 0 K limit, the structural thermal domain (STD) size of crystalline and amorphous materials can be obtained. The difference of white hair and normal black hair from heat conduction perspective is reported for the first time. Loss of melanin results in a worse thermal protection and a larger STD size in the white hair. By reviewing the different variation of thermal reffusivity against decreasing temperature profiles, we conclude that they reflected the structural connection in the materials. Ultimately, the future application of thermal reffusivity theory in studying 2D materials and amorphous materials is discussed.

关键词: thermal reffusivity theory     phonon behavior     structure defects     structural thermal domain (STD) size     2D material     amorphous material    

电磁超材料:从新物理现象到新信息系统 Review Articles

Rui-yuan WU, Tie-jun CUI

《信息与电子工程前沿(英文)》 2020年 第21卷 第1期   页码 4-26 doi: 10.1631/FITEE.1900465

摘要: 由于对电磁波强大的调控能力,超材料和超表面吸引了越来越多研究者的关注。本文回顾总结近年来电磁超材料的发展,从最初的新物理现象到现在的新信息系统。首先展示等效媒质超材料的定义和应用,包括隐身衣和超材料透镜等。随后介绍二维超材料,即电磁超表面,对空间波和表面波的调控功能,同时概述表面等离子激元及其在微波段的应用。在此基础上,着重介绍新颖的数字编码超材料和可编程超材料,统称信息超材料。通过将理论层的信息科学与物理层的超材料设计联系在一起,实现一系列新型器件和系统,同时实现信息和电磁波调控。最后,对超材料的未来发展做出展望。

关键词: 超材料;等效媒质理论;超表面;表面等离子激元;数字编码;可编程;信息    

表面"彩虹"上的超分辨率光谱位移传感 Article

Lyu Zhou, Nan Zhang, Chang Chieh Hsu, Matthew Singer, Xie Zeng, Yizheng Li, Haomin Song, Josep Jornet, Yun Wu, Qiaoqiang Gan

《工程(英文)》 2022年 第17卷 第10期   页码 75-81 doi: 10.1016/j.eng.2022.03.018

摘要:

高精度的亚波长光波操纵在光谱学、传感和医学成像中可实现令人兴奋的新颖应用。这些应用中理想的目标是可实现光谱信息片上分析的小型化光谱仪。特别地,对于基于成像系统的光谱传感机制,其关键挑战是如何实现精准的空间信息分辨(即波长偏移或生物、化学表面结合引起的空间位移),这类似于超分辨率成像所带来的挑战。本文中,我们报道了一种特殊的可以捕获“彩虹”的超表面,并将其应用于芯片光谱仪和传感器。结合超分辨图像处理,通过低设置4×光学显微镜系统可分辨出等离子体“彩虹”捕获超表面上35 nm范围内共振位置的位移,同时该超表面的面积小至0.002 mm2。这种可实现高效耦合的“彩虹”等离子体共振空间操纵的独特特征为小型化片上光谱分析提供了一个新的平台,其光谱分辨率为0.032 nm波长偏移。通过使用该低设置4×光学显微镜成像系统,我们展示了A549 外泌体的生物传感分辨率为1.92×109个∙mL−1,并使用外泌体表皮生长因子受体(EGFR)的表达值来区分患者样本和健康对照样本,从而展示了一种精确特异性生物/化学传感检测应用的新型片上传感系统。

关键词: “彩虹”捕获     超表面     表面等离子体激元     超分辨位移     片上生物传感    

Cell surface protein engineering for high-performance whole-cell catalysts

Hajime Nakatani,Katsutoshi Hori

《化学科学与工程前沿(英文)》 2017年 第11卷 第1期   页码 46-57 doi: 10.1007/s11705-017-1609-3

摘要: Cell surface protein engineering facilitated by accumulation of information on genome and protein structure involves heterologous production and modification of cell surface proteins using genetic engineering, and is important for the development of high-performance whole-cell catalysts. In this field, cell surface display is a major technology by exposing target proteins, such as enzymes, on the cell surface using a carrier protein. The target proteins are fused to the carrier proteins that transport and tether them to the cell surface, as well as to a secretion signal. This paper reviews cell surface display systems for prokaryotic and eukaryotic cells from the perspective of carrier proteins, which determine the number of displayed molecules, and the localization, size, and direction ( or terminal anchoring) of the passengers. We also discuss advanced methods for displaying multiple enzymes and a new method for the immobilization of whole-cell catalysts using adhesive surface proteins.

关键词: cell surface engineering     surface display     whole-cell catalysts     bioprocess    

An Exploration of Surface Integrity Remanufacturing for Aeroengine Components

Qiao Xiang,Yong He,Ting-hong Hou

《工程管理前沿(英文)》 2016年 第3卷 第2期   页码 107-114 doi: 10.15302/J-FEM-2016025

摘要: Surface integrity is the major factor impacting on the operation quality, service life and reliability of the aeroengine components. The surface integrity of aeroengine component is damaged by the failures such as crack, deformation, oxidation, corrosion, erosion, and microstructural degeneration. It adopts advanced remanufacturing technologies to restore or improve the surface integrity and regenerate these high value parts. This paper firstly puts forward the concept, namely surface integrity remanufacturing for aeroengine components, and its connotation. The key remanufacturing technologies have been developed to repair the components with surface damages. Ultimately, some application examples of surface integrity remanufacturing technologies as well as their effects in aeroengine maintenance are introduced. The discarded components have been reused and their service lives have been extended and their reliability has been increased by implementing surface integrity remanufacturing. It has realized “The Repaired Components Outpacing the New Ones”, material saving, energy saving, and emission reduction.

关键词: aeroengine component     surface integrity     remanufacturing     surface integrity remanufacturing    

Review on mechanism and process of surface polishing using lasers

Arun KRISHNAN, Fengzhou FANG

《机械工程前沿(英文)》 2019年 第14卷 第3期   页码 299-319 doi: 10.1007/s11465-019-0535-0

摘要: Laser polishing is a technology of smoothening the surface of various materials with highly intense laser beams. When these beams impact on the material surface to be polished, the surface starts to be melted due to the high temperature. The melted material is then relocated from the ‘peaks to valleys’ under the multidirectional action of surface tension. By varying the process parameters such as beam intensity, energy density, spot diameter, and feed rate, different rates of surface roughness can be achieved. High precision polishing of surfaces can be done using laser process. Currently, laser polishing has extended its applications from photonics to molds as well as bio-medical sectors. Conventional polishing techniques have many drawbacks such as less capability of polishing freeform surfaces, environmental pollution, long processing time, and health hazards for the operators. Laser polishing on the other hand eliminates all the mentioned drawbacks and comes as a promising technology that can be relied for smoothening of initial topography of the surfaces irrespective of the complexity of the surface. Majority of the researchers performed laser polishing on materials such as steel, titanium, and its alloys because of its low cost and reliability. This article gives a detailed overview of the laser polishing mechanism by explaining various process parameters briefly to get a better understanding about the entire polishing process. The advantages and applications are also explained clearly to have a good knowledge about the importance of laser polishing in the future.

关键词: laser polishing     surface roughness     process parameters     mechanism    

Largely reduced cross-plane thermal conductivity of nanoporous In

Dongchao XU, Quan WANG, Xuewang WU, Jie ZHU, Hongbo ZHAO, Bo XIAO, Xiaojia WANG, Xiaoliang WANG, Qing HAO

《能源前沿(英文)》 2018年 第12卷 第1期   页码 127-136 doi: 10.1007/s11708-018-0519-5

摘要: In recent year, nanoporous Si thin films have been widely studied for their potential applications in thermoelectrics, in which high thermoelectric performance can be obtained by combining both the dramatically reduced lattice thermal conductivity and bulk-like electrical properties. Along this line, a high thermoelectric figure of merit (ZT) is also anticipated for other nanoporous thin films, whose bulk counterparts possess superior electrical properties but also high lattice thermal conductivities. Numerous thermoelectric studies have been carried out on Si-based nanoporous thin films, whereas cost-effective nitrides and oxides are not systematically studied for similar thermoelectric benefits. In this work, the cross-plane thermal conductivities of nanoporous In Ga N thin films with varied porous patterns were measured with the time-domain thermoreflectance technique. These alloys are suggested to have better electrical properties than conventional Si Ge alloys; however, a high ZT is hindered by their intrinsically high lattice thermal conductivity, which can be addressed by introducing nanopores to scatter phonons. In contrast to previous studies using dry-etched nanopores with amorphous pore edges, the measured nanoporous thin films of this work are directly grown on a patterned sapphire substrate to minimize the structural damage by dry etching. This removes the uncertainty in the phonon transport analysis due to amorphous pore edges. Based on the measurement results, remarkable phonon size effects can be found for a thin film with periodic 300-nm-diameter pores of different patterns. This indicates that a significant amount of heat inside these alloys is still carried by phonons with ~300 nm or longer mean free paths. Our studies provide important guidance for ZT enhancement in alloys of nitrides and similar oxides.

关键词: nanoporous film     thermoelectrics     phonon     mean free path     diffusive scattering    

Tribological study on the surface modification of metal-on-polymer bioimplants

《机械工程前沿(英文)》 2022年 第17卷 第2期 doi: 10.1007/s11465-022-0682-6

摘要: The tribological performance of artificial joints is regarded as the main factor of the lifespan of implanted prostheses. The relationship between surface roughness and coefficient of friction (COF) under dry and lubricated conditions is studied. Results show that under dry test, friction coefficient is not reduced all the time with a decrease in surface roughness. On the contrary, a threshold of roughness value is observed, and frictional force increases again below this value. This critical value lies between 40 and 100 nm in Sa (roughness). This phenomenon is due to the transfer of friction mechanisms from abrasion to adhesion. Under wet test, COF always decreases with reduction in surface roughness. This result is mainly attributed to the existence of a thin layer of lubricant film that prevents the intimate contact of two articulating surfaces, thus greatly alleviating adhesion friction. Furthermore, surface texturing technology is successful in improving the corresponding tribological performance by decreasing friction force and mitigating surface deterioration. The even-distribution mode of texturing patterns is most suitable for artificial joints. By obtaining the optimal surface roughness and applying texturing technology, the tribological performance of polymer-based bioimplants can be greatly enhanced.

关键词: artificial joints     surface roughness     friction     surface texturing    

Development of surface reconstruction algorithms for optical interferometric measurement

Dongxu WU, Fengzhou FANG

《机械工程前沿(英文)》 2021年 第16卷 第1期   页码 1-31 doi: 10.1007/s11465-020-0602-6

摘要: Optical interferometry is a powerful tool for measuring and characterizing areal surface topography in precision manufacturing. A variety of instruments based on optical interferometry have been developed to meet the measurement needs in various applications, but the existing techniques are simply not enough to meet the ever-increasing requirements in terms of accuracy, speed, robustness, and dynamic range, especially in on-line or on-machine conditions. This paper provides an in-depth perspective of surface topography reconstruction for optical interferometric measurements. Principles, configurations, and applications of typical optical interferometers with different capabilities and limitations are presented. Theoretical background and recent advances of fringe analysis algorithms, including coherence peak sensing and phase-shifting algorithm, are summarized. The new developments in measurement accuracy and repeatability, noise resistance, self-calibration ability, and computational efficiency are discussed. This paper also presents the new challenges that optical interferometry techniques are facing in surface topography measurement. To address these challenges, advanced techniques in image stitching, on-machine measurement, intelligent sampling, parallel computing, and deep learning are explored to improve the functional performance of optical interferometry in future manufacturing metrology.

关键词: surface topography     measurement     optical interferometry     coherence envelope     phase-shifting algorithm    

Hysteretic behavior of cambered surface steel tube damper: Theoretical and experimental research

《结构与土木工程前沿(英文)》 2023年 第17卷 第4期   页码 606-624 doi: 10.1007/s11709-023-0925-6

摘要: A novel cambered surface steel tube damper (CSTD) with a cambered surface steel tube and two concave connecting plates is proposed herein. The steel tube is the main energy dissipation component and comprises a weakened segment in the middle, a transition segment, and an embedded segment. It is believed that during an earthquake, the middle weakened segment of the CSTD will be damaged, whereas the reliability of the end connection is ensured. Theoretical and experimental studies are conducted to verify the effectiveness of the proposed CSTD. Formulas for the initial stiffness and yield force of the CSTD are proposed. Subsequently, two CSTD specimens with different steel tube thicknesses are fabricated and tested under cyclic quasi-static loads. The result shows that the CSTD yields a stable hysteretic response and affords excellent energy dissipation. A parametric study is conducted to investigate the effects of the steel tube height, diameter, and thickness on the seismic performance of the CSTD. Compared with equal-stiffness design steel tube dampers, the CSTD exhibits better energy dissipation performance, more stable hysteretic response, and better uniformity in plastic deformation distributions.

关键词: cambered surface steel tube damper     energy dissipation capacity     finite element model     hysteretic performance     parametric study    

Materials and surface engineering to control bacterial adhesion and biofilm formation: A review of recent

Huan GU, Dacheng REN

《化学科学与工程前沿(英文)》 2014年 第8卷 第1期   页码 20-33 doi: 10.1007/s11705-014-1412-3

摘要: Bacterial adhesion to surfaces and subsequent biofilm formation are a leading cause of chronic infections and biofouling. These processes are highly sensitive to environmental factors and present a challenge to research using traditional approaches with uncontrolled surfaces. Recent advances in materials research and surface engineering have brought exciting opportunities to pattern bacterial cell clusters and to obtain synthetic biofilms with well-controlled cell density and morphology of cell clusters. In this article, we will review the recent achievements in this field and comment on the future directions.

关键词: surface engineering     materials     bacterial adhesion     biofilm     control     review    

Dynamic response surface methodology using Lasso regression for organic pharmaceutical synthesis

《化学科学与工程前沿(英文)》 2022年 第16卷 第2期   页码 221-236 doi: 10.1007/s11705-021-2061-y

摘要: To study the dynamic behavior of a process, time-resolved data are collected at different time instants during each of a series of experiments, which are usually designed with the design of experiments or the design of dynamic experiments methodologies. For utilizing such time-resolved data to model the dynamic behavior, dynamic response surface methodology (DRSM), a data-driven modeling method, has been proposed. Two approaches can be adopted in the estimation of the model parameters: stepwise regression, used in several of previous publications, and Lasso regression, which is newly incorporated in this paper for the estimation of DRSM models. Here, we show that both approaches yield similarly accurate models, while the computational time of Lasso is on average two magnitude smaller. Two case studies are performed to show the advantages of the proposed method. In the first case study, where the concentrations of different species are modeled directly, DRSM method provides more accurate models compared to the models in the literature. The second case study, where the reaction extents are modeled instead of the species concentrations, illustrates the versatility of the DRSM methodology. Therefore, DRSM with Lasso regression can provide faster and more accurate data-driven models for a variety of organic synthesis datasets.

关键词: data-driven modeling     pharmaceutical organic synthesis     Lasso regression     dynamic response surface methodology    

Improved blending strategy for membrane modification by virtue of surface segregation using surface-tailored

Shuai Liang, Peng Gao, Xiaoqi Gao, Kang Xiao, Xia Huang

《环境科学与工程前沿(英文)》 2016年 第10卷 第6期 doi: 10.1007/s11783-016-0875-5

摘要: Two types of amphiphilic nanoparticles were prepared via silanization reaction. Amphiphilic nanoparticles tend to protrude from membrane matrix by segregation. Blending with amphiphilic nanoparticles further enhances membrane hydrophilicity. Excessive silanization cause adverse effect on blending efficiency. Membrane modification is one of the most feasible and effective solutions to membrane fouling problem which tenaciously hampered the further augmentation of membrane separation technology. Blending modification with nanoparticles (NPs), owing to the convenience of being incorporated in established membrane production lines, possesses an advantageous viability in practical applications. However, the existing blending strategy suffers from a low utilization efficiency due to NP encasement by membrane matrix. The current study proposed an improved blending modification approach with amphiphilic NPs (aNPs), which were prepared through silanization using 3-(Trimethoxysilyl)propyl methacrylate (TMSPMA) as coupling agents and ZnO or SiO as pristine NPs (pNPs), respectively. The Fourier transform infrared and X-ray photoelectron spectroscopy analyses revealed the presence of appropriate organic components in both the ZnO and SiO aNPs, which verified the success of the silanization process. As compared with the pristine and conventional pNP-blended membranes, both the ZnO aNP-blended and SiO aNP-blended membranes with proper silanization (100% and 200% w/w) achieved a significantly increased blending efficiency with more NPs scattering on the internal and external membrane surfaces under scanning electron microscope observation. This improvement contributed to the increase of membrane hydrophilicity. Nevertheless, an extra dosage of the TMSPMA led to an encasement of NPs, thereby adversely affecting the properties of the resultant membranes. On the basis of all the tests, 100% (w/w) was selected as the optimum TMSPMA dosage for blending modification for both the ZnO and SiO types.

关键词: Membrane modification     Nanoparticle     Hydrophilic     Amphiphilic     Blending    

Radiative properties of materials with surface scattering or volume scattering: A review

Qunzhi ZHU, Hyunjin LEE, Zhuomin M. HANG

《能源前沿(英文)》 2009年 第3卷 第1期   页码 60-79 doi: 10.1007/s11708-009-0011-3

摘要: Radiative properties of rough surfaces, particulate media and porous materials are important in thermal engineerit transfer between surfaces and volume elements in participating media, as well as for accurate radiometric temperature measurements. In this paper, recent research on scattering of thermal radiation by rough surfaces, fibrous insulation, soot, aerogel, biological materials, and polytetrafluoroethylene (PTFE) was reviewed. Both theoretical modeling and experimental investigation are discussed. Rigorous solutions and approximation methods for surface scattering and volume scattering are described. The approach of using measured surface roughness statistics in Monte Carlo simulations to predict radiative properties of rough surfaces is emphasized. The effects of various parameters on the radiative properties of particulate media and porous materials are summarized.

关键词: aerogel     fiber     particle scattering     radiative properties     soot     surface roughness    

标题 作者 时间 类型 操作

Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

期刊论文

Thermal reffusivity: uncovering phonon behavior, structural defects, and domain size

Yangsu XIE, Bowen ZHU, Jing LIU, Zaoli XU, Xinwei WANG

期刊论文

电磁超材料:从新物理现象到新信息系统

Rui-yuan WU, Tie-jun CUI

期刊论文

表面"彩虹"上的超分辨率光谱位移传感

Lyu Zhou, Nan Zhang, Chang Chieh Hsu, Matthew Singer, Xie Zeng, Yizheng Li, Haomin Song, Josep Jornet, Yun Wu, Qiaoqiang Gan

期刊论文

Cell surface protein engineering for high-performance whole-cell catalysts

Hajime Nakatani,Katsutoshi Hori

期刊论文

An Exploration of Surface Integrity Remanufacturing for Aeroengine Components

Qiao Xiang,Yong He,Ting-hong Hou

期刊论文

Review on mechanism and process of surface polishing using lasers

Arun KRISHNAN, Fengzhou FANG

期刊论文

Largely reduced cross-plane thermal conductivity of nanoporous In

Dongchao XU, Quan WANG, Xuewang WU, Jie ZHU, Hongbo ZHAO, Bo XIAO, Xiaojia WANG, Xiaoliang WANG, Qing HAO

期刊论文

Tribological study on the surface modification of metal-on-polymer bioimplants

期刊论文

Development of surface reconstruction algorithms for optical interferometric measurement

Dongxu WU, Fengzhou FANG

期刊论文

Hysteretic behavior of cambered surface steel tube damper: Theoretical and experimental research

期刊论文

Materials and surface engineering to control bacterial adhesion and biofilm formation: A review of recent

Huan GU, Dacheng REN

期刊论文

Dynamic response surface methodology using Lasso regression for organic pharmaceutical synthesis

期刊论文

Improved blending strategy for membrane modification by virtue of surface segregation using surface-tailored

Shuai Liang, Peng Gao, Xiaoqi Gao, Kang Xiao, Xia Huang

期刊论文

Radiative properties of materials with surface scattering or volume scattering: A review

Qunzhi ZHU, Hyunjin LEE, Zhuomin M. HANG

期刊论文